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/Title (Contribution la purification de dchets de silicium solaire oxyd laide dun procd assist par plasma thermique)
/Author (Matthias DE SOUSA)
/Creator (PDFCreator 2.0.2.0)
/ModDate (D:20150216135524+01'00')
/Subject (La dcoupe de wafers gnre des quantits importantes de dchets de silicium de grade solaire qui ne sont pas revaloriss actuellement cause de la contamination lors du procd de dcoupe. Les travaux prsents dans ce manuscrit portent sur ltude de la purification de dchets de silicium solaire laide dun procd assist par une torche plasma darc non transfr. Cette tude a t mene selon une double approche numrique et exprimentale. Les calculs numriques ont t raliss laide dun code de calcul de mcanique des fluides. Ils sont utiliss pour dimensionner la configuration exprimentale et pour comprendre linfluence des paramtres opratoires sur lcoulement gazeux et le traitement des particules. Ltude exprimentale a consist injecter des dchets pulvrulents de silicium \(sciures de silicium, poudre de concassage\) dans un jet de plasma sous atmosphre contrle puis les collecter dans un creuset chaud. La dsoxydation et la dcarburation de dchets de silicium, notamment de la sciure issue de la dcoupe des wafers, a t mise en vidence laide du procd dvelopp. Toutefois, llimination des impurets mtalliques dans les sciures de silicium na pas t dmontre lors de cette tude. Les rsultats exprimentaux et numriques ont mis en vidence que la dsoxydation est amliore avec un jet de plasma lent ainsi quavec une teneur en air rsiduelle limite dans la zone de traitement. La carborduction de la silice ainsi que la volatilisation de la silice par oxydation du silicium semblent tre les deux mcanismes de purification mis en jeu lors du procd.)
/Keywords ("sciure de silicium, plasma thermique, purification, dsoxydation")
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/CreationDate (D:20150216104040+01'00')
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sciure de silicium, plasma thermique, purification, désoxydation
2015-02-16T13:55:24+01:00
2015-02-16T10:40:40+01:00
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Contribution à la purification de déchets de silicium solaire oxydé à l’aide d’un procédé assisté par plasma thermique
Matthias DE SOUSA
La découpe de wafers génère des quantités importantes de déchets de silicium de grade solaire qui ne sont pas revalorisés actuellement à cause de la contamination lors du procédé de découpe. Les travaux présentés dans ce manuscrit portent sur l’étude de la purification de déchets de silicium solaire à l’aide d’un procédé assisté par une torche à plasma d’arc non transféré. Cette étude a été menée selon une double approche numérique et expérimentale. Les calculs numériques ont été réalisés à l’aide d’un code de calcul de mécanique des fluides. Ils sont utilisés pour dimensionner la configuration expérimentale et pour comprendre l’influence des paramètres opératoires sur l’écoulement gazeux et le traitement des particules. L’étude expérimentale a consisté à ’injecter des déchets pulvérulents de silicium (sciures de silicium, poudre de concassage) dans un jet de plasma sous atmosphère contrôlée puis à les collecter dans un creuset chaud. La désoxydation et la décarburation de déchets de silicium, notamment de la sciure issue de la découpe des wafers, a été mise en évidence à l’aide du procédé développé. Toutefois, l’élimination des impuretés métalliques dans les sciures de silicium n’a pas été démontrée lors de cette étude. Les résultats expérimentaux et numériques ont mis en évidence que la désoxydation est améliorée avec un jet de plasma lent ainsi qu’avec une teneur en air résiduelle limitée dans la zone de traitement. La carboréduction de la silice ainsi que la volatilisation de la silice par oxydation du silicium semblent être les deux mécanismes de purification mis en jeu lors du procédé.
sciure de silicium, plasma thermique, purification, désoxydation
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